Spectrophotometric determination of platinum metals. V.* Determination of palladium with Pyrogallol Red
نویسنده
چکیده
A new spectrophotometric method for the determination of palladium with Pyrogallol Red is described. Its high sensitivity is dependent on the presence of micellar system of 1-carbethoxypentadecyltrimethylammonium bromide, which leads to the maximum colour formation in acid solutions (pH 5.5) in a shorter time interval than in the absence of tenside. The ternary pal ladium-dye-cation-active tenside system obeys the Beer law over the range 0.20—3.70 pig ml Pd(II), with sensitivity index according to Sandell 5 = 4 x 10~ ug cm" and a molar absorptivity of e' = 2.6 x 101 mol" cm" at the maximum of the differential curve at 620 nm.
منابع مشابه
Kinetic-Spectrophotometric Determination of Thiocyanate Based on Its Inhibitory Effect on the Oxidation of Pyrogallol Red by Bromate
A kinetic spectrophotometric method for rapid measurement of thiocyanate in serum, urine and sewage water with no need for removed of interfering substances in described. The method is based on the inhibitory effect of thiocyanate on the oxidation of pyrogallol red by bromated and nitrite which is monitored at 467 nm. The variables affecting the rate of the reaction were investigated and th...
متن کاملApplication of Differential Kinetic Method Using ANN with a New Synthetic Reagent for Simultaneous Spectrophotometric Determination of Mercury and Palladium
A new selective reagent was used for simultaneous determination of mercury and palladium in real samples with their different kinetic spectrophotometric properties. The method is based on the difference in the rate of the oxidation reaction of the recently synthesized reagent, nitro benzoyl diphenylmethylen phosphorane (N-BDMP), with Hg2+ and Pd2+. The kinetic profiles were monitored and record...
متن کاملExtraction - Spectrophotometric Determination of Palladium with Tetrabutyl Ammonium Iodide
A sensitive and selective extraction - spectrophotometric method for the determination of trace amounts of palladium is reported. The method is based on quantitative extraction of brownish tetrabutylammoium tetraiodopalladium (II) ion pair into a small valume of chloroform at pH 1.3-12.0, followed by spectrophotometric measurements. The Beer's law is obeyed over the range 0.02-1.09 <em...
متن کاملUltra-trace Determination of Palladium(II) by Spectrophotometric Flow Injection Analysis
Nowadays, palladium compounds due to their especial characteristics used in different industries, mainly in electrical power sources and chemical productions as a catalyst. Therefore, Pd concentration is increasing in our around that can be contaminant our environment due its toxic effects. In this work, a simple, selective and rapid flow injection method of analysis (FIA) has been developed fo...
متن کاملDIFFERENTIAL PULSE POLAROGRAPHIC DETERMINATION OF OSMIUM BY CATALYSIS OF PYROGALLOL-RED BROMATE REACTION
A highly sensitive differential pulse polarographic (DPP) method has been developed for the determination of trace amounts of osmium, based on the catalytic effect of osmium (VIII) on the oxidation of pyrogallol red (PGR) by sodium bromate at pH 7.00 and 25.0 0.1 ? C. The reaction rate was monitored by measuring the differential pulse cathodic current of the oxidation product of PGR and broma...
متن کامل